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Sodium Periodate Sodium periodate can refer to two different chemical compounds which are essentially sodium salts of the two varieties of periodate ion. Sodium metaperiodate (often abbreviated as m-periodate) has the formula NaIO4. Sodium orthoperiodate (often abbreviated as o-periodate) has the formula Na5IO6. Both salts are useful in certain synthetic chemistries for the oxidative power of the periodate ion.
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